Bis(6-methoxy-1-methyl-2,3,4,9-tetrahydro-1H-β-carbolin-2-ium) tetrachloridozincate(II) dihydrate
نویسندگان
چکیده
The asymmetric unit of the title compound, (C(13)H(17)N(2)O)(2)[ZnCl(4)]·2H(2)O, contains two tetra-hydro-harmine cations, one tetra-chloro-zincate(II) anion and two water mol-ecules. In the cations, the two 1H-indole ring systems are essentially planar, with maximum deviations of 0.016 (2) and 0.018 (2) Å, and both tetra-hydro-pyridinium rings show a half-chair conformation. The Zn(II) complex anion has a distorted tetra-hedral geometry. In the crystal, inter-molecular N-H⋯O, N-H⋯Cl, O-H⋯O, O-H⋯Cl and C-H⋯O hydrogen bonds link the components into a three-dimensional network. A π-π inter-action with a centroid-centroid distance of 3.542 (14) Å is also observed.
منابع مشابه
6-Methoxy-1-(4-methoxyphenyl)-1,2,3,4-tetrahydro-9H-β-carbolin-2-ium acetate
In the title compound, C(19)H(21)N(2)O(2) (+)·C(2)H(3)O(2) (-), the 1H-indole ring system is essentially planar [maximum deviation = 0.0257 (14) Å] and forms a dihedral angle of 87.92 (7) Å with the benzene ring attached to the tetra-hydro-pyridinium fragment. The tetra-hydro-pyridinium ring adopts a half-chair conformation. In the crystal, cations and anions are linked by inter-ionic N-H⋯O, C-...
متن کاملBis(2-trifluoromethyl-1H-benzimidazol-3-ium) tetrachloridomercurate dihydrate
In the title compound, (C(8)H(6)F(3)N(2))(2)[HgCl(4)]·2H(2)O, the Hg(II) cation is coordinated by four Cl(-) anions in a distorted tetra-hedral geometry. In the crystal, the 2-trifluoro-methyl-1H-benzimidazolium cations link to the [HgCl(4)](2-) complex anions and lattice water mol-ecules via N-H⋯Cl and N-H⋯O hydrogen bonds, and the lattice water mol-ecules further link to the Hg complex anion ...
متن کاملBis(7-methoxy-1-methyl-4,9-dihydro-3H-β-carbolinium) tetrachloridozincate
In the title compound, (C(13)H(15)N(2)O)(2)[ZnCl(4)], also known as di(harmalinium) tetra-chloridozincate, the Zn(II) atom is in a distorted tetrahedral coordination of the chlorido ligands. In the cation, the meth-oxy and methyl groups are both coplanar with with rings to which they are attached [maximum deviations of 0.232 (4) and 0.259 (4) Å, respectively]. In the crystal, the alkaloid catio...
متن کامل6-Methoxy-2,3,4,9-tetrahydro-1H-carbazol-1-one
The carbazole unit of the title mol-ecule, C(13)H(13)NO(2), is not planar. The dihedral angle between the benzene ring and the pyrrole ring is 1.69 (6)°. The cyclo-hexene ring adopts an envelope conformation. Inter-molecular C-H⋯O and N-H⋯O hydrogen bonds are present in the crystal structure. A C-H⋯π inter-action, involving the benzene ring, is also found in the crystal structure.
متن کاملBis(2-methyl-1H-imidazol-3-ium) naphthalene-1,5-disulfonate dihydrate
The asymmetric unit of the title organic salt, 2C(4)H(7)N(2) (+)·C(10)H(6)O(6)S(2) (2-)·2H(2)O, consists of a 2-methyl-imidazolium cation, a half of a naphthalene-1,5-disulfonate anion, which lies about a center of symmetry, and a water mol-ecule. In the crystal, N-H⋯O and O-H⋯O hydrogen bonds link the cations, anions and water mol-ecules into the layers parallel to (111).
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012